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The ligand-directed C—H activation relies on a coordinating donor atom being in proximity to the C—H bond activated. Cyclometallation of 2-(1-naphthyl)-pyridine – a substrate containing both γ- and δ-positions in proximity to the directing nitrogen atom – was studied. Cycloruthenation and cyclopalladation result in γ-substitution and formation of the corresponding 5-membered metallacycles, which i

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The purpose of this essay is to investigate the validity of the hypothesis that there is a negative relationship between female official representation and the level of corruption in developing states. The possibility of a reversed causality is also considered. This is done through statistical analysis combined with a theoretical framework. The results show a weak relationship between the level o