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Thermochemistry of metallic alkyls : Part 7. - The heat of formation of mercury diphenyl, and of mercury phenyl chloride

The heat of reaction of mercury diphenyl with hydrogen chloride in benzene solvent has been measured at 25°C. The heat of reaction of mercury diphenyl with mercuric chloride in methanol solvent has also been measured. From these heats of reaction, the heat of formation of mercury diphenyl has been derived: ΔHf° (Hgφ2, cryst.) = 65.4 ± 2 kcal/mole. Previous data on the heats of reaction of mercury

The evidence that exercise during growth or adulthood reduces the risk of fragility fractures is weak

There has never been, and will never be, a randomized double-blind placebo-controlled trial demonstrating that exercise in youth, adulthood or old age reduces fragility or osteoporosis-related fractures in old age. The next level of evidence, a randomized, controlled but unblinded study with fractures as an end-point is feasible but has never been done. The basis for the belief that exercise reduc

Lipase-catalyzed transesterification of phosphatidylcholine at controlled water activity

The incorporation of a free fatty acid into the sn-1 position of phosphatidylcholine by lipase-catalyzed transesterification was investigated. The thermodynamic water activity of both the enzyme preparation and the substrate solution was adjusted to the same value prior to the reaction. The reaction rate increased with increasing water activity but the yield of modified phosphatidylcholine decreas

Decentralized Intelligence in Freight Transport - a Critical Review

The purpose of this paper is to provide a research outlook on the concept of decentralized freight intelligence, i.e. autonomous freight making localized routing decisions. A review of research literature on decentralized intelligence in freight transport serves as the foundation of the analysis. The analysis reveals a scarcity of scientific evidence to suggest a successful introduction of decentr

XAFS study of Cu(II) at the water-goethite (alpha-FeOOH) interface

Cu(II) complexation at the water-goethite (alpha-FeOOH) interface was studied by XAFS, potentiometry, and sorption experiments. Thermodynamic data indicate that the initial Cu(II) sorption is not accompanied by release of a H+. As pH is raised, hydrolysis occurs, and a maximum of two H+ are released per sorbed ion. Sorption experiments also show that Cu(II) complexation is insensitive to variation

Value and Unacceptable Risk: Temkin's Worries about Continuity Reconsidered

Consider a transitive value ordering of outcomes and lotteries on outcomes, which satisfies substitutivity of equivalents and obeys ‘continuity for easy cases’, i. e., allows compensating risks of small losses by chances of small improvements. Temkin (2001) has argued that such an ordering must also - rather counter-intuitively - allow chances of small improvements to compensate risks of huge loss

Evidence in action: a Thompsonian perspective on evidence-based decision-making in social work

Evidence-based practice presupposes evidence-based decision-making. In the debate it is argued that a social work fashioned after evidence should be more rational, less authoritarian and built on scientific knowledge, respect and ethics. Yet the empirical evidence that this idea works is weak. In fact the difficulties met during efforts to implement evidence could be a sound reaction. Indeed diffi

Two BRCA1-positive epithelial ovarian tumors with metastases to the central nervous system: a case report

BACKGROUND: Cerebral metastasis secondary to ovarian cancer is a rare phenomenon. While no clear relationship to known prognostic factors is found, others suggest this as a biologically diverse behavior of ovarian cancer. CASES: In a pilot study, 37 invasive epithelial ovarian cancer samples were analyzed to detect the frequency of BRCA1/BRCA2 mutations in the south of Sweden (results published).

Retreat from Salix - Swedish experience with energy crops in the 1990s

A wave of Salix (willow) planting rolled over Sweden in the early 1990s, driven by subsidies and optimistic market expectations. The expected economic life span of such investments is 20 years or more. But in fact, many plantations were terminated or reduced much sooner. This article explores the reasons for this retreat. In a survey to Salix farmers, 41 per cent either have retreated or regretted

CFD analysis on the dynamic flow characteristics of the pilot-control globe valve

The pilot-control globe valve (PCGV) is a new kind valve with simple structures and low driving energy consumption. It can utilize the pressure difference before and after the valve to control the action of the valve core. However, systematic theoretical research and numerical analysis are deficient at present. In this paper, the mathematical model of PCGV is established and Computational Fluid Dy

The second Team Haemophilia Education Meeting, 2016, Frankfurt, Germany

The first Team Haemophilia Education (THE) Meeting was held on 7–8 May 2015 in Amsterdam, The Netherlands. It aimed to promote the optimal care of patients with haemophilia through education of the multidisciplinary treatment team. This was achieved by reviewing the latest developments in haemophilia management, considering how these can be implemented in the clinic to improve patient care and pro

Combining Text Semantics and Image Geometry to Improve Scene Interpretation

Inthispaper,wedescribeanovelsystemthatidentifiesrelationsbetweentheobjectsextractedfromanimage. We started from the idea that in addition to the geometric and visual properties of the image objects, we could exploit lexical and semantic information from the text accompanying the image. As experimental set up, we gathered a corpus of images from Wikipedia as well as their associated articles. We ext

Exocomet signatures around the A-shell star φ Leonis?

We present an intensive monitoring of high-resolution spectra of the Ca ii K line in the A7IV shell star φ Leo at very short (minutes, hours), short (night to night), and medium (weeks, months) timescales. The spectra show remarkable variable absorptions on timescales of hours, days, and months. The characteristics of these sporadic events are very similar to most that are observed toward the debr

Assessment of risk reduction strategies for terrorist attacks on structures

Attacks on infrastructure have been a common feature of terrorism over many decades. The weapon of choice is often a Vehicle-Borne Improvised Explosive Device (VBIED) or a person-borne or other type of IED. The consequences of a successful attack in terms of casualties, physical damage, and other direct and indirect costs including societal costs can be catastrophic. Protectives and other risk red

Inheriting “Difficult Histories” : National Identities, Memory Debates and Cultural Diversity

For some reason, modern European nations have traditionally presented themselves as having a lot of rich and important history, much of it portrayed as being “international” in terms of cultural impact and wider global significance. Today, much of this history appears to be far more controversial than many comfortable national-popular narratives have acknowledged. This article explores how Europe

A New Model Inspired by the Pompeii Worm to Reverse Overheating in Nanosatellites

“Those who are inspired by a model other than Nature, a mistress above all masters, are labouring in vain.” attributed to Leonardo DaVinci Nanosatellites are exposed to extreme temperatures on the spacecraft surface, which can reach up to ±100 °C. In this paper, we suggest a novel solution to this challenge by the use of biomimicry. The imitation of the behavior of living creatures in nature is an

Advocating access to justice: Facilitating or gatekeeping?

Advocacy is one of the central means for supporting access to justice. The social work profession has advocacy as one of its main courses of action. This discusses the components in actions that are considered as good practice for facilitating access to justice in its democratic aspects. More explicitly social workers advocacy for promoting the worth and dignity of human beings in society. Four di