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Structure of Tetrafluorocyclopropane, Hexafluorocyclobutene, Octofluorocyclopentene, and Related Perfluoroalkene Radical Anions Revealed by ESR Spectroscopic and Computational Studies

Isotropic and anisotropic ESR spectra were observed for the radical anions of hexafluorocyclobutene (c-C4F6-), octafluorocyclopentene (c-C5F8-) and perfluoro-2-butene (CF3CFCFCF3-) in γ-irradiated plastically crystalline neopentane, tetramethylsilane (TMS) and TMS-d12 matrices, or the rigid 2-methyltetrahydrofuran (MTHF) matrix. The isotropic spectra of c-C4F6- and c-C5F8- are characterized by thr

The Tragedy of the Commoners: The Decline of the Customary Marine Tenure System of Tonga

The breakdown of traditional marine tenure systems and overexploitation of marine organisms as a result of rapid modernization, urbanization and population growth in the case of Tonga is outlined. The customary marine tenure system is described and the threats against the coral reefs are discussed. It is shown how accumulative strategies correlate with the move toward overexploitation. It is argue

PES Studies of Ru(dcbpyH2)2(NCS)2 Adsorption on Nanostructured ZnO for Solar Cell Applications

The interaction between the dye cis-bis(4,4‘-dicarboxy-2,2‘-bipyridine)-bis(isothiocyanato)-ruthenium(II), Ru(dcbpyH2)2(NCS)2, and nanostructured ZnO was investigated by photoelectron spectroscopy (PES) using synchrotron radiation. The results are compared with those of nanostructured TiO2 sensitized with the same dye, which to date is the most efficient system for dye-sensitized photoelectrochemi

Photoinduced electron transfer between a carotenoid and TiO2 nanoparticle

The dynamics of photoinduced electron injection and recombination between all-trans-8'-apo-beta-caroten-8'-oic acid (ACOA) and a TiO2 Colloidal nanoparticle have been studied by means of transient absorption spectroscopy. We observed an ultrafast (similar to360 fs) electron injection from the initially excited S-2 state of ACOA into the TiO2 conduction band with a quantum yield of similar to40%. A

Molecular mapping of the Goodpasture's epitope for glomerulonephritis

Goodpasture's syndrome is an autoimmune disease characterized by pulmonary hemorrhage, glomerulonephritis, and antiglomerular basement membrane (GBM) antibodies. We have studied a rat model with chimeric proteins (CPs) consisting of portions of the nephritogenic non-collagenous domain of alpha3 type IV collagen (alpha3(IV)NC1) and non-nephritogenic alpha1(IV)NC1. CPs with aminoterminal alpha3 that

Spectroscopic data for Hg I and Hg II from beam-foil spectroscopy

The spectroscopic data mercury (Hg) I and Hg II was analyzed from beam-foil spectroscopy. The wavelength was found to be of course fixed and independent of the light source and recording conditions. It was found that if the calculated branching ratio was correct, then the Hg II was an important constituent of fluorescent light tube plasmas. The wavelength region from 40 to 600 nm in overlapping wa

HAMLET - In vivo effects and mechanisms of tumor-cell death

Popular Abstract in Swedish Ämnen i bröstmjölk kan få cancerceller att begå självmord - in vivo effekter och mekanismer för celldöd Sedan länge är det känt att bröstmjölk skyddar det ammande barnet mot infektioner och hjälper till att bygga upp des's immunförsvar. Ett skyddande ämne som kan bilda's av molekyler från bröstmjölk är HAMLET (human alpha-lactalbumin made lethal to tumor cell's), som kHAMLET (human alpha-lactalbumin made lethal to tumor cells), a molecular complex derived from human milk, is an interesting new tool in cancer research since it induces programmed cell death in tumor cells while leaving normal, differentiated cells unharmed. The in vivo effects of HAMLET were studied in a rat xenograft model of human glioblastoma. HAMLET reduced the tumor volume and delayed the o

Properties of long gamma-ray bursts from massive compact binaries.

We consider the implications of a model for long-duration gamma-ray bursts in which the progenitor is spun up in a close binary by tidal interactions with a massive black-hole companion. We investigate a sample of such binaries produced by a binary population synthesis, and show that the model predicts several common features in the accretion on to the newly formed black hole. In all cases, the ac

Into the isle of self : Nietzschean patterns and contrasts in D.H. Lawrence's The trespasser

This thesis is based on a close reading of Lawrence's novel The Trespasser from a Nietzschean point of view. By adopting this perspective it aims at giving the novel the sense of unity it has so far been alleged to lack. The analysis is preceded by a detailed discussion of the concept of literary influence. Since the purpose of this study is to illuminate what is unique in Lawrence's novel rather

Capture and evolution of dust in planetary mean-motion resonances: a fast, semi-analytic method for generating resonantly trapped disc images

Dust grains migrating under Poynting-Robertson drag may be trapped in mean-motion resonances with planets. Such resonantly trapped grains are observed in the Solar system. In extrasolar systems, the exozodiacal light produced by dust grains is expected to be a major obstacle to future missions attempting to directly image terrestrial planets. The patterns made by resonantly trapped dust, however,

Spaces of urbanity. From the village square to the boulevard

Urbanism is much more than simply an agglomeration of houses : it is a particular way of living space. Our considerations starts out from some of the historically prominent figures of urbanity, such as the market-place, the boulevard and the coffee house. Semiotics of space may either involve a certain number of elementary building-blocks being combined in particular ways, much as language is ; or

Of Red Threads and Green Dragons: Austrian Sociotechnical Imaginaries about STI cooperation with China

In this chapter, we address intersections of Science and Technology Studies (STS) and International Relations Theories (IR) by looking at how Austrian science, technology & innovation (STI) policy makers and related stakeholders envision and enact a close relationship between China and Austria in the field of green technologies. Analytically, we draw on the concept of ‘sociotechnical imaginari

Fashion, Sociology of

Fashion's universal nature does not preclude strong variations in its significance from society to society. As a stratification variable, fashion's importance increases in step with economic growth. Simmel sees the ‘need for distinction’ and the ‘need for union’ as preconditions for fashion, with certain societies lacking the necessary motivation. Variations in fashion's importance have also been

Transdisciplinarity in rammed earth construction for contemporary practice

Abstract in UndeterminedFor centuries rammed earth has been a method of construction in various parts of the world. It is an economical building technique as earth is an abundant cheap resource. It is durable, safe and a desirable building technique for hot climates. This paper is discussing a workshop activity in building with sustainable rammed earth construction methods in Egypt. It adds to pre