Filetype
The Pd atom in the title compound, [Pd(CHP)Cl], has a distorted square-planar CClP coordination geometry with the ,,'-tridentate ligand forming two five-membered metallacycles. The cyclo-hexane ring is aligned with the Pd coordination plane due to C-H activation in an equatorial position, giving a tri-equatorial conformation of the cyclo-hexyl ring.
The title compound, C13H16O2, is a chiral bicyclic structure composed of two fused cyclohexane rings possessing both boat and chair conformations. The molecules are packed in enantiopure columns which are pairwise linked forming an overall racemic solid; within the column pairs the packing is governed by weak dipole-dipole interactions stemming from stacked carbonyl functionalities (COcentroid-COc
The Pd-II atom in the title compound, [Pd(C2F3O2)(C24H43P2)], adopts a distorted square-planar geometry with the P atoms in a trans arrangement, forming two five-membered chelate rings. Four intramolecular C-H center dot center dot center dot O hydrogen bonds occur. The crystal packing reveals one weak intermolecular C-H center dot center dot center dot O hydrogen bond, which self-assembles the mo
The title compound, [PtCl(C32H27P2)], has a pseudo-square-planar coordination geometry around the Pt atom with the P,C,P'-tridentate ligand forming two five-membered rings that are tilted with respect to the coordination plane. The two Pt-P the Pt-Cl and the Pt-C distances are 2.2794 (9)/2.2749 (10), 2.3831 (10) and 2.002 (3) Angstrom, respectively.
The title compound, [PdBr(C24H49P2)], has a distorted square-planar coordination geometry with the P, C, P'-tridentate ligand forming two five-membered chelate rings. The Br atom is displaced from the square plane by 0.560 (6) angstrom.
Music in different forms is significant in young people’s lives. Due to the media revolution in our modern society, children of today learn a lot about music on their own by taking part in an increasing production of musical cultures. In this paper different forms of play is applied as a way to reach a deeper understanding of children’s creative music making. This article describes a 2-year empiri
This data package contains high accuracy CO2 dry air mole fractions from 58 ICOS and non-ICOS European observatories at in total 132 observation levels, collected by the ICOS Atmosphere Thematic Centre (ATC) and provided by the station contributors. The package is part of the Globalviewplus v8.0 data product, released in 2022 and is intended for use in carbon cycle inverse modeling, model evaluati
