The influence of permeant properties on the sorption step in hydrophobic pervaporation.
Liquid solubility measurements were performed by immersion of poly(octyl)methylsiloxane (POMS) in dilute aqueous solutions of homologous series of aliphatic esters and alcohols with compound specific concentrations of 20, 40, 80 and 120 ppm. Measurements were performed at 20 °C with both single- and multi-compound mixtures and linear sorption isotherms were obtained. By fitting experimentally dete