Sökresultat

The rate constants for the chloride and bromide anations of Pd(H2O)42+, the chloride anations of PdCl3H2O−, the bromide anation of PdBr3H2O− and the acid hydrolysis of PdCl(H2O)3+, PdBr(H2O)3+, PdCl42−, and PdBr42− have been determined at 15, 25 and 35 °C using a stopped-flow technique. The ionic strength was 1.00 M and the supporting electrolyte perchloric acid. The obtained rate constants and thThe rate constants for the chloride and bromide anations of Pd(H2O)42+, the chloride anations of PdCl3H2O−, the bromide anation of PdBr3H2O− and the acid hydrolysis of PdCl(H2O)3+, PdBr(H2O)3+, PdCl42−, and PdBr42− have been determined at 15, 25 and 35 °C using a stopped-flow technique. The ionic strength was 1.00 M and the supporting electrolyte perchloric acid. The obtained rate constants and th

We previously identified osteopontin (OPN) as a promising marker for the early detection of hepatocellular carcinoma (HCC). In this study, we investigated the association between prediagnostic circulating OPN levels and HCC incidence in a large population-based cohort. A nested case-control study was conducted within the European Prospective Investigation into Cancer and Nutrition (EPIC) cohort. D

Syftet med detta utkast är att analysera uppfattningar om brott i Bosnien under och efter kriget samt beskriva i vilken mån inblandande parter i en konflikt kan förlåta varandra eller försonas. Den empiriska delen bygger på observationer i Ljubija, en stad i nordvästra Bosnien, tidningsartiklar från området samt fjorton intervjuer. Under krigets normupplösning sker vissa brott som kan vara antig

Although platelets are best known as primary mediators of hemostasis, this function intimately associates them with inflammatory processes, and it has been increasingly recognized that platelets play an active role in both innate and adaptive immunity. For example, platelet adhesive interactions with leukocytes and endothelial cells via P-selectin can lead to several pro-inflammatory events, inclu

The purpose of this paper is to describe a novel approach to economic evaluation of infrastructure, the benefit analyses in the Swedish high-speed rail project, and to analyse what role these can play in the decision-making process. The reports identify benefits from infrastructure investment at the local level and were intended to assist in making co-financing agreements and as a basis for decisi

Critical infrastructure systems must be both robust and resilient in order to ensure the functioning of society. To improve the performance of such systems, we often use risk and vulnerability analysis to nd and address system weaknesses. A critical component of such analyses is the ability to accurately determine the negative consequences of various types of failures in the system. Numerous mathe

The poetry of place is usually thought of as a form of nature writing imbued in the material and local, contrasting themes and motifs of the literary convention with authenticity and concretion. John Keats tends, on the contrary, to be associated with the attempt to escape materiality, favoring instead the artificial blessings of imagination. Unsurprisingly, few ecocritical studies have taken an iThe poetry of place is usually thought of as a form of nature writing imbued in the material and local, contrasting themes and motifs of the literary convention with authenticity and concretion. John Keats tends, on the contrary, to be associated with the attempt to escape materiality, favoring instead the artificial blessings of imagination. Unsurprisingly, few ecocritical studies have taken an i

The chiral tetradentate N4-donor ligand, 1-methyl-2-({(S)-2-[(S)-1-(1-methylbenzimidazol-2-yl methyl)pyrrolidin-2-yl]pyrrolidin-1-yl}methyl) benzimidazole (S,S- PDBz L), based on a chiral dipyrrolidine backbone, has been synthesized and its corresponding Fe(ii) complex has been prepared and characterized. The X-ray structure of the complex reveals that the Fe(ii) ion is in a distorted octahedral

During recent years new threats have accentuated the role of scientific experts for creating risk awareness, understanding, and advice for action or preparedness for informed risk decisions. Scientific experts are expected to engage in risk communication with stakeholders at various levels, not least the general public. Scientific experts exist in organizations where forms and goals may vary, as w

Dynamic glucose enhanced (DGE) chemical exchange saturation transfer (CEST) MRI is an emerging imaging technique that provides a molecular-specific type of image contrast, based on magnetic labelling of exchangeable protons. The technique enables the use of biodegradable sugars as contrast agents, and such compounds are believed to have less side effects than conventional MRI contrast agents. HoweDynamic glucose enhanced (DGE) chemical exchange saturation transfer (CEST) MRI is an emerging imaging technique that provides a molecular-specific type of image contrast, based on magnetic labelling of exchangeable protons. The technique enables the use of biodegradable sugars as contrast agents, and such compounds are believed to have less side effects than conventional MRI contrast agents. Howe

Two hydride compounds with aliphatic pincer ligands, (PCyP)IrH2 (PCyP = {cis-1,3-bis[(di-tert-butylphosphino)methyl]cyclohexane}- (1) and (PCyP)IrH4 (2), have been studied, with emphasis on features where such systems differ from arene-based analogues. Both compounds reveal relatively rapid exchange between α-C-H and Ir-H, which can occur via formation of carbene or through demetalation, with near

Elasticity and damping are significant properties of rubber, taken advantage of in engineering applications. It is therefore important that the constitutive model accurately captures these aspects of the mechanical behavior. In the first part of the thesis a description of theory and experiments for determination of hyperelastic parameters required for finite element analysis is provided. Test sp

Objective. The aim of the current study was to investigate whether genetic variation in genes across the serotoninergic system is associated with chronic widespread pain (CWP) and the number of pain sites reported. Methods. A discovery cohort, with pain data at 3 time points, was used to investigate genetic associations with 2 phenotypes: 1) CWP (at >= 2 time points; n = 164) compared with pain-fr

Hospital. Not a positive word. Children + Hospital. Create an even more unpleasant feeling. When you arrive to the Children´s Hospital in Lund, you enter a dark but wide corridor. A busy doctor may scurry across the fl oor and disappear behind an alarmed door. If the reception is unmanned, the grey metallic venetian blinds are closed. It is hard to understand where to go. Even a grown-up can feel

Violence against children occurs worldwide despite explicit prohibitions. In Article 19 in the United Nations Convention on the Rights of the Child there is a prohibition against physical and psychological violence towards children. States shall take all appropriate legislative, administrative, social and educational measures to protect the child. According to Article 23 (4) the convention state

The increased competition for talented employees is a new challenge for todays organizations to reach success and as a response to this challenge the term Talent Management was developed during the 1990s. Due to the relatively new concept there is still no generally accepted definition and the purpose of this study is to contribute with knowledge about what defines Talent Management and how it has

Denna studie tillämpar Van Dijks kritiska diskursanalys på tre tal som hölls av George W.Bush, Laura Bush samt Collin Powell under år 2001 efter attackerna på World Trade Center. I och med att de i dessa tre tal hävdar att kriget mot terrorismen även är en kamp för de afghanska kvinnornas rättigheter, är det av relevans att tillämpa en kritisk diskursanalys för att identifiera relevanta retoriska

Cystitis is a bacterial infection of the bladder that occurs in about half of women at least once in their lifetime. Antibiotics such as nitrofurantoin are used to treat cystitis, but antibiotic resistance is a concern, especially for recurrent infections. Here we report an open-label, randomized, single-centre, phase 2 study to analyse the acute and long-term safety and efficacy of the IL-1 recep

The digestion of food is known to have significant hemodynamic and metabolic effects where many have not been fully investigated. The potential effect of food intake could be interesting both from a physiological point of view and from a methodological point of view, as it could affect when blood samples are collected. The objective of this study was to investigate the effect of food intake on 143