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A short and efficient total synthesis of rac-desoxygaliellalactone and (+)-desoxygaliellalactone, via the biosynthetic intermediate pregaliellalactone, is described. The synthesis was achieved in only three steps, for (+)-desoxygaliellalactone including an enantioselective alkyl propiolate addition to 4-pentenal, a palladium catalysed alkylative lactonisation and an intramolecular Diels-Alder cycl
Popular Abstract in Swedish Den här avhandlingen innehåller fyra uppsatser som på ett eller annat sätt relaterar till befolkningsströmningar såsom dess ekonomiska konsekvenser och orsaker. I den första uppsatsen används en hushållsundersökning från Kina för att undersöka huruvida utbildning bidrar till att höja inkomsterna hos hushåll i jordbrukssektorn. Genom regressionsanalys uppmäts korrelatioAbstract Population movements are more substantial today than at any other point in human history. If managed effectively, migration can be beneficial for all aspects of social and economic life. This thesis contains four papers, all of which are related to the economic consequences and determinants of migration, within and across countries. The first paper employs a household survey to explore
Current response and gain spectrum of a terahertz quantum cascade laser is analyzed at different temperatures by a nonequilibrium Green's functions approach. The simulations are compared to recent results of time domain spectroscopy. Being able to retrieve higher harmonics of the response function, nonlinear phenomena in quantum cascade lasers are studied theoretically. For different temperatures,
The objective of this paper is to provide a general account of value relations. But it takes its departure is a special type of value relation, parity. The notion of parity is due to Ruth Chang. According to her, two items may be evaluatively comparable even when neither is better than, worse than, or equally good as the other. There is a fourth kind of comparability: being on a par. Recently, Jos
Using constant-effort catch data, causes of annual variation in the timing of migration of Curlew Sandpipers (Calidris ferruginea) migrating through Ottenby, Sweden, as well as the trend in timing of migration from 1946-2005, was investigated. Variation in the timing of autumn migration of adult and juvenile Curlew Sandpipers was influenced by breeding success connected to predation pressure on th
Using the Swedish military enlistment test, this paper estimates the return to schooling for individuals belonging to different parts of the ability distribution. It also attempts to predict whether an endogenous test score causes bias in the "ability-specific" returns to schooling that varies with the test score. A significant finding is that a higher score in the test is associated with a higher
This paper examines Sweden’s role as a pioneer in mitigating climate change. Critical discourse analysis of climate and energy policy unveils Sweden’s ambition to ‘lead-by-example’, by virtue of a win-win combination of economy and environment via stringent regulations and an early-mover strategy on eco-innovations. The extent of the unilateral approach is constrained by concerns for the competiti
The epidermal growth factor receptor (EGFR) and the estrogen receptor (ER) modulator Amplified In Breast cancer-1 (AIB1) have been reported to be of importance for the prognosis of breast cancer patients. We have analyzed AIB1 and EGFR by immunohistochemistry in primary breast cancers (n = 297) arranged in a tissue microarray in order to predict outcome after adjuvant endocrine therapy with tamoxi
This thesis measures cost efficiency in the production of health care and social services in Sweden. The object of analysis is not provider efficiency, but instead the relative efficiency of political organizations or different contractual arrangements. The thesis focuses on: 1) the measurement of cost efficiency, 2) the investigation of potential trade-offs between quantity of health care service
Novel magneto-resistive memory effect is demonstrated, which appears in lithographically patterned Y-shaped, three-terminal nanostructures, consisting of three nanowires joined in one point, formed in the epitaxial layer of a ferromagnetic (Ga, Mn) As semiconductor. The effect, in which the zero-field resistance of a pair of nanowires depends on the direction of the previously applied magnetic fie
A transceiver suitable for devices in wireless body area networks is presented. Stringent requirements are imposed by the high link loss between opposite sides of the body, about 85 dB in the 2.45 GHz ISM band. Despite this, minimum physical size and power consumption are required, and we target a transceiver with 1 mm2 chip area, 1 mW active power consumption, and data rate 250 kbit/s. The receiv
Methanol oxidation to formaldehyde was studied over a series of Fe-Mo-O catalysts with various Mo/Fe atomic ratio and the end compositions Fe2O3 and MoO3. The activity data shows that the specific activity passes through a maximum with increase of the Mo content and is the highest for Fe2(MoO4)3. The selectivity to formaldehyde, on the other hand, increases with the Mo content in the catalyst. A s
Zinc protoporphyrin is formed in pork homogenates in both enzymatic and non-enzymatic reactions. Ferrochelatase is active in formation of the highly fluorescent pigment known from Parma ham as demonstrated by inhibition with N-methylmesoporphyrin and by thermal inactivation. A non-enzymatic transmetallisation reaction, exchange of iron in myoglobin by zinc(II), is demonstrated by Pb(II) inhibition
Prasugrel, a novel P2Y(12) ADP-receptor antagonist, has been reported to achieve greater inhibition of platelet aggregation compared to clopidogrel as assessed by light transmission aggregometry. It was the objective of this study to investigate the effect of prasugrel on alternative markers of platelet activation in comparison to a high loading dose and the approved maintenance dose of clopidogre
We examined whether zinc transporter-8 autoantibodies (ZnT8A; arginine ZnT8-RA, tryptophan ZnT8-WA, and glutamine ZnT8-QA variants) differed between immigrant and Swedish patients due to different polymorphisms of SLC30A8, HLA-DQ, or both. Newly diagnosed autoimmune (≥1 islet autoantibody) T1D type 1 diabetic patients (n = 2,964, <18 years, 55% male) were ascertained in the Better Diabetes Diagnos
